Abstract

The standard format for cylindrical Li-ion cells is about to change from 18650-type cells (18mm diameter, 65mm height) to 21700-type cells (21mm diameter, 70mm height). We investigated the properties of five 18650 cells, three of the first commercially available 21700, and three types of the similar 20700 cells in detail. In particular, the (i) specific energy/energy density and electrode thickness, (ii) electrode area and cell resistance, (iii) specific energy as a function of discharge C-rate, as well as (iv) heating behavior due to current flow are analyzed. Finally, the production effort for cells and packs are roughly estimated for 21700 cells compared to 18650 cells.

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