Abstract
Energy bands formed by rotation–vibrational states of molecules in the presence of symmetry and their qualitative modifications under variation of some control parameters are studied within the semi-quantum model. Rotational variables are treated as classical whereas a finite set of vibrational states is considered as quantum. In the two-state approximation the system is described in terms of a fiber bundle with the base space being a two-dimensional sphere, the classical phase space for rotational variables. Generically this rank 2 complex vector bundle can be decomposed into two complex line bundles characterized by a topological invariant, the first Chern class. A general method of explicit calculation of Chern classes and of their possible modifications under variation of control parameters in the presence of symmetry is suggested. The construction of iso-Chern diagrams which split the space of control parameters into connected domains with fixed Chern numbers is suggested. A detailed analysis of the rovibrational model Hamiltonian for a D 3 invariant molecule possessing two vibrational states transforming according to the two-dimensional irreducible representation is done to illustrate non-trivial restrictions imposed by symmetry on possible values of Chern classes.
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