Energy and Air Pollutants in Belgium: The Contribution of Automotive Traffic since 1980

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Energy and Air Pollutants in Belgium: The Contribution of Automotive Traffic since 1980

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  • Research Article
  • Cite Count Icon 27
  • 10.1021/ie9602724
Effect of Oxygen Vacancy on CO−NO−O2Reaction over Yttria-Stabilized Zirconia-Supported Copper Oxide Catalyst
  • May 1, 1997
  • Industrial & Engineering Chemistry Research
  • Chin-Cheng Chien + 2 more

The effect of oxygen vacancy on the enhancement of activity of CO−NO−O2 reaction over yttria-stabilized zirconia (YSZ)-supported CuO catalyst was investigated in the present study. The catalysts were prepared by the impregnation method, and their characteristics were studied by temperature-programmed reduction. The catalyst was placed in a flow reactor for performing the temperature-programmed reaction, and the effluent gas was analyzed by an on-line NOx analyzer, consisting of a chemiluminescence unit and two gas chromatographs in series. The present results indicate that copper oxide supported by YSZ exhibits a higher catalytic activity than that supported by α-Al2O3, for the CO−NO−O2 reaction. The enhanced activity is inferred to result from the formation of interfacial Cu2O and the oxygen-ion transfer. Additionally, the probable effect of oxygen vacancy in promoting the CO−O2 or CO−NO2 reaction has been elucidated by a mechanism involving oxygen-ion transfer via surface oxygen vacancies of YSZ, which are located at the interface between CuO and YSZ. It was found that the CuO/YSZ catalyst is a promising substitute for the conventional Rh/alumina catalyst.

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  • 10.1016/s0167-2991(98)80860-4
Contribution of fossil fuels and air pollutants emissions in Belgium since 1980 the role of traffic
  • Jan 1, 1998
  • Studies in Surface Science and Catalysis
  • Walter Hecq

Contribution of fossil fuels and air pollutants emissions in Belgium since 1980 the role of traffic

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Atmospheric Emissions from Sources of Air Pollution in Petroleum Industry-Emission Inventory
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  • L Romic + 1 more

Three main categories of pollutant emissions into the atmosphere from Croatian oil and natural gas activities are: fuel combustion, fugitive and carbon dioxide separated from natural gas. The pollutants (or pollutant classes) emitted into the air are: main greenhouse gases such as CO2, CH4; indirect greenhouse gases such as NOx, CO and NMVOC gases (with no direct greenhouse effect, but they influence generation and disintegration of tropospheric and stratospheric ozon who has properties of a greenhouse gases); suspended particulate matter (SPM) and sulphur dioxide (SO2). These pollutants are emitted into the air during normal well operations, production, processing and distribution of gas and oil products. SNAP94 for CORINAIR inventory three level hierarchical emission source nomenclatures (covers 4 main sectors, 9 sub-sectors and 33 activities) has been used to characterise the cause of the emissions and to relate it to anthropogenic activity in petroleum industry. Point, line and area sources of air pollution in petroleum industry are considered. Emission estimations are based on detailed activity/technology information covering stationary sources. IPCC simplified method (Tier 1-production based average emission factor approach) for estimating CO2 non-CO2 greenhouse gases emissions, based on activity level and average emission factors, has been used. EMEP/CORINAIR detailed method (mass balance approach) to estimate fugitive emissions of ozone precursors (NOx, CO and NMVOC) from oil and natural gas activities has been also used. Comparison (in graph form) between emissions of air pollutants from INA- Petroleum Industry and emissions in Croatia has been made. Introduction Three main categories of pollutant emissions into the atmosphere from INA Croatian petroleum industry are: fuel combustion, fugitive emissions and emissions of carbon dioxide removed from natural gas. Fuel combustion result in emissions of carbon dioxide (CO2), and non-CO2 emissions such as emissions of methane (CH4), nitrous oxide (N2O), oxides of nitrogen (NOx), carbon monoxide (CO), nonmethane volatile organic compounds (NMVOC) and sulfur dioxide (SO2). Result of fugitive emissions are emissions of methane from oil and natural gas activities, emissions of ozone percursors (CO, NOx, NMVOC) and emission of SO2 from oil refining. Removal of CO2 by amine scrubbing result in subseqent emissions of CO2 into the atmosphere. The emissions of these polutants influence the air quality on local, regional and global level. Local level: Emissions of NOx, SO2, (fines) suspended particulate matter (SPM), heavy metals (HM), such as Pb, Hg, Cd, As, Ni and smoke from emission sources (stationary fuel combustion, oil refining) at petroleum refineries contribute to air quality in the urban areas where refineries are located (Rijeka, Sisak). Today, ground level concentrations of SO2 and soot at the sources at petrolum rafineries primarily due to combustion of gas instead of liquid fuel has been decreased to degree that the air quality at this urban areas belongs to first category. Regional level: Emissions from petroleum industry contribute to the problems on regional level, such as acid rains (SO2, NOx), eutrophication (NOx), high concentrations of tropospheric ozon (NOx), and pollutions with heavy metals and persistent organic pollutants (POP) such as polycyclic aromatic hydrocarbons (PAH) and dioxin. According to data, emissions of SO2, NOx from refineries (Sisak, Rijeka) contribute with 8 percent to total emissions of SO2, NOx from liquid fuels in Croatia (1).

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Ports in a Storm
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In many parts of the world, shipping-related emissions have already exceeded or are expected to soon exceed those from land-based sources. Shipping emissions can be reduced substantially by using some of the same technologies being applied to land-based sources, including cleaner engines and fuels, exhaust control methods, and operational modifications. Various ports are testing the feasibility of these mechanisms with varying degrees of success. What is perhaps most greatly needed is expedited creation of better regulations at all levels, from the International Maritime Organization to port city authorities.

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Installing PEMS on an Offshore Oil and Gas Complex: Developing Atmospheric Emissions Abatement Strategies with Reliable Scientific Data
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TOTAL Abu Al Bukhoosh (TABK) is an offshore Oil and Gas facility producing an average of 100 000 boepd. This activity is inevitably associated with environmental impacts and in particular with atmospheric emissions of greenhouse gases (GHG). Fully adhering to international strive to curb GHG emission, TABK has implemented innovative solutions by equipping all its air pollution emission sources (flares, power generation turbines and gas compression turbines) with Predictive Emissions Monitoring Systems (PEMS). PEMS are software based continuous monitoring systems that are using process data such as, but not limited to, fuel consumption, power output, combustion exhaust temperature, etc to predict air pollutant emissions. PEMS models were designed, tested, and certified in compliance with current best international practices and now allows TABK to continuously quantify the emissions of nitrogen oxides (NOx), sulphur dioxide (SO2), carbon monoxide (CO), oxygen (O2) and carbon dioxide (CO2) on its offshore facility. Results indicate that atmospheric emissions have a direct correlation with operation of the emission source; load, firing temperature, fuel flow and quality. Calibrated emissions models utilize measurements from existing instruments already available in the site control system (DCS) and calculate, display, trend and report the emissions of NOx, CO, O2, SO2, CO2. PEMS reporting solution was granted approval by ADNOC, the local regulator, and is recognized as being a Best Available Technique for UAE Integrated Pollution Prevention and Control emissions compliance reporting. Furthermore, this continuous quantification of the main air pollutant emissions can now support adequate modeling and assessment that enables accurate air quality forecasting and can support any development of cost-effective abatement philosophy and strategy with clear and precise scientific information.

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Improving the Air Quality Management: The Air Pollutant and Carbon Emission and Air Quality Model for Air Pollutant and Carbon Emission Reduction in the Iron and Steel Industries of Tangshan, Hebei Province, China
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Currently, Tangshan confronts the dual challenge of elevated carbon emissions and substantial pollution discharge from the iron and steel industries (ISIs). While significant efforts have been made to mitigate air pollutants and carbon emissions within the ISIs, there remains a gap in comprehending the control of carbon emissions, air pollutant emissions, and their contributions to air pollutant concentrations at the enterprise level. In this study, we devised the Air Pollutant and Carbon Emission and Air Quality (ACEA) model to identify enterprises with noteworthy air pollution and carbon emissions, as well as substantial contributions to air pollutant concentrations. We constructed a detailed inventory of air pollutants and CO2 emissions from the iron and steel industry in Tangshan for the year 2019. The findings reveal that in 2019, Tangshan emitted 5.75 × 104 t of SO2, 13.47 × 104 t of NOx, 3.55 × 104 t of PM10, 1.80 × 104 t of PM2.5, 5.79 × 106 t of CO and 219.62 Mt of CO2. The ACEA model effectively pinpointed key links between ISI enterprises emitting air pollutants and carbon dioxide, notably in pre-iron-making processes (coking, sintering, pelletizing) and the Blast furnace. By utilizing the developed air pollutant emission inventory, the CALPUFF model assessed the impact of ISI enterprises on air quality in the Tangshan region. Subsequently, we graded the performance of air pollutant and CO2 emissions following established criteria. The ACEA model successfully identified eight enterprises with significant air pollution and carbon emissions, exerting notable influence on air pollutant concentrations. Furthermore, the ACEA outcomes offer the potential for enhancing regional air quality in Tangshan and provide a scientific instrument for mitigating air pollutants and carbon emissions. The effective application of the ACEA model in Tangshan’s steel industry holds promise for supporting carbon reduction initiatives and elevating environmental standards in other industrial cities across China.

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Air pollution, both indoors and outdoors, is a major environmental health problem affecting everyone in developed and developing countries alike. Any agent that spoils air quality is called air pollutant. Air pollution can be defined as the presence of pollutants,such as sulphur dioxide (SO2), particle substances (PM), nitrogen oxides (NOX) and ozone (O3) in the air that we inhale at levels which can create some negative effects on the environment and human health (Bayram, 2006). Air pollutants have sources that are both natural and human-based. Now, humans contribute substantially more to the air pollution problem. Though some pollution comes from natural sources, most pollution is the result of human activity. Air pollution is a problem of growing importance. This pollution damages the natural processes in the atmosphere, and affects public health negatively. Currently, several cities stand out as worst cases of air pollution (Kilburn,1992). It was found that until the 1980s, 1.3 billion people lived in cities where pollution was above the air quality standards (Bayram, 2006). Besides, air pollution is a main threat to the vegetation. Pollutants such as dust, soot, fog, steam, ash, smoke, etc. are introduced into air naturally and as a result of human activities. The athmosphere can neutralize toxic solid, liquid and gaseous substances by melting them; however, due to the production of excessive amounts of such substances and depending on the meteorological and topographic conditions, the atmosphere is in a continuous process of pollution. (Kaypak and Ozdilek,2008). There are several main types of pollution. Among the main pollutants in the urban atmosphere are primarily the particle substances (PM), sulphur dioxide (SO2), nitrogen oxides (NOx), volatile organic compounds (VOCs), and secondarily ozone (O3) that is created as a result of photochemical reactions. (Ozden et all.,2008). Particles are introduced into the air by burning fuel for energy. The gases produced as a result of burning fuels in automobiles, homes, and industries are a major source of pollution in the air. The exhaust from burning fuels in automobiles, homes, and industries is a major source of pollution in the air. Some believe that even the burning of wood and charcoal in fireplaces and barbeques can release significant quanitites of soot into the air. Another type of pollution is the release of noxious gases, such as sulfur dioxide, carbon monoxide, nitrogen oxides, and chemical vapors. These can take part in further chemical reactions once they are in the atmosphere, forming smog and acid rain (URL4). Air pollution was first seen in Turkey as a serious problem in the early 1970s, and in the following years it spread into other cities mainly Istanbul. The reason for this is that lignite

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The primary driver of atmospheric pollution is humanity's demand for energy. Consequently, traffic and industry—particularly the energy sector—are considered the dominant sources of air pollution. Intensive motorized traffic significantly contributes to increased vehicular emissions, negatively impacting the atmosphere and all the environment. A range of negative effects of air pollution is observed, particularly in the urban environment, where one of the most considerable is the impact on human health. Air pollution affects all living organisms, leading to various health issues, including respiratory and cardiovascular diseases, allergic reactions, and even death. Due to urbanization, the prevalence of respiratory conditions, such as allergic asthma, chronic obstructive bronchitis, and chronic obstructive pulmonary disease, is increasing. Literature data shows that the emission of air pollutants (e.g. particulate matter, sulfur or nitrogen oxides) in developing countries, like Serbia, is higher than in industrialized ones. The study deals with the analysis of the health data and air pollutants emission data related to the energy sector and road traffic in Serbia, establishing the dynamic change trend in the period 2012-2022. Trend change dynamics were followed for the main air pollutants like black carbon, particulate matter, nitrogen dioxide, Sulphur dioxide, carbon monoxide, ammonia, and non-methane volatile organic compounds. The analysis showed the positive trend changes in the dominant air pollutants emission relevant for the observed industry sectors, during the 11 years. The emission rate of NO<sub>2</sub> from road transport in the period 2012 - 2022 shows a positive trend of change, and the share of NO<sub>2</sub> in total emission increased from 19.87% to 41.06%. Also, share of black carbon and various particulate matter in total national emission increased. Regarding the coal-power plant as a dominant energy source and a primary source of SO<sub>2</sub> emissions in Serbia, its emission rate fluctuated during the observed period. Nevertheless, its contribution to the total national emissions increased from 90.30% in 2012 to 95.56% in 2022. Regarding the results, future monitoring of the air pollutants emission level and implementing measures to improve the air quality in Serbia should be of high importance. Therefore, investment towards green transition and traffic planning, including the number and types of vehicles within urban areas, as a critical factor in mitigating air pollution levels, should be a priority. Furthermore, policies related to reducing air pollution emission from diverse sources should be harmonized with the European Union's regulatory framework to ensure alignment with empirical outcomes.

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