Abstract
We report dielectric barrier discharge (DBD)‐based atmospheric pressure (AP) plasma polymerization (PP) experiments using argon carrier gas and a wide variety of hydrocarbon molecules as the precursors (“monomers”). As in our preceding research with other reagents, unprecedented precision and reproducibility in energy measurements is again demonstrated. Measurements based on various aliphatic and aromatic hydrocarbon compounds have yielded values of Em, the energy absorbed from the plasma by each monomer molecule. Systematic differences among families of compounds enabled us to draw several important conclusions about fragmentation and polymerization in the DBD plasma environment, observations which are in fair qualitative agreement with low‐pressure radio‐frequency PP data by Yasuda and Hirotsu from the 1970s.
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