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https://doi.org/10.1002/anie.200461823
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Cite Publication Date: Jan 18, 2005 | |
 Citations: 67 |
Affiliation: University of Stuttgart, Goethe University Frankfurt
Key steps in the convergent enantioselective synthesis of the cytotoxic natural product (see structural formula) are tandem Michael addition/electrophilic trapping reactions, Sonogashira coupling, Julia–Kocienski olefination, and macrocyclization. Formation of the tetramic acid completed the synthesis.
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