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https://doi.org/10.1016/s0040-4039(01)82028-1
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Cite Journal: Tetrahedron Letters |  Publication Date: Jan 1, 1981 |
 Citations: 39 |
Affiliation: Colorado State University
The major precursor to the maytansinoids containing 4 non-racemic chiral centers has been prepared in gram quantities, suitable for further synthesis. The route to (+)- 1 was accomplished in 13 steps including several highly stereocontrolled reactions which precluded resolutions or separations.
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