Abstract
A practical synthetic method of chiral γ-trimethylsilylmethyl allylic alcohols ( 1 ) with both E- and Z-configuration has been developed. The alcohols 1 are readily converted into 1-vinyl-1,2-diols ( 5 ) via diastereoselective epoxidation followed by the reaction with nBu 4NF. The conversion of 1 into vinyl epoxides or α,β-dialkoxy aldehydes is also carried out.
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