Abstract
AbstractLewis‐base‐catalyzed asymmetric hydrosilylation of substituted benzophenone N‐aryl imines was investigated. Among various chiral Lewis‐base catalysts, a catalyst derived from L‐Serine was found to be the most favorable one which promote the reaction to afford a series of (diarylmethyl)amines with high yields (up to 97 %) in moderate to good enantioselectivities (up to 97 % ee). The absolute configuration of the product was determined by the X‐ray crystallographic analysis.magnified image
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