Abstract
Studies of the perturbing effect of the trifluoromethylanthryl carbinol used as chiral solvating agent (CSA) upon the 1H NMR spectra of chiral α-O-substituted β-hydroxylamides demonstrated the ability of this fluoroalcohol to afford diastereomeric solvates with these solutes. Thus, for all the tested amides, there is at least one possibility to proceed to their enantiomeric discrimination by 1H NMR using CSA. The method was developed to determine (later and indirectly) a possible chiral recognition during in vitro enzymatic hydrolysis in locust biological tissues of N-acylaziridines conceived as proinsecticides of carboxylic acids, in view to eventually optimize their efficiency.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
