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https://doi.org/10.1021/ja202874d
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Cite Publication Date: May 19, 2011 | |
 Citations: 69 |
Affiliation: Tokushima University
Enantiocontrolled total syntheses of the breviones A, B, and C have been accomplished using a highly diastereoselective oxidative coupling of an α-pyrone with a tricyclic diene prepared from an optically pure Wieland-Miescher ketone derivative through the 7-endo-trig mode of acyl radical cyclization.
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