EMISSIONS OF GREENHOUSE GASES FROM UKRAINIAN THERMAL POWER PLANTS

Energy-related activities are a major contributor of greenhouse gas (GHG) emissions. A growing body of knowledge clearly depicts the links between human activities and climate change. Over the last century the burning of fossil fuels such as coal and oil and other human activities has released carbon dioxide (CO2) emissions and other heat-trapping GHG emissions into the atmosphere and thus increased the concentration of atmospheric CO2 emissions. The main human activities that emit CO2 emissions are (1) the combustion of fossil fuels to generate electricity, accounting for about 37% of total U.S. CO2 emissions and 31% of total U.S. GHG emissions in 2013, (2) the combustion of fossil fuels such as gasoline and diesel to transport people and goods, accounting for about 31% of total U.S. CO2 emissions and 26% of total U.S. GHG emissions in 2013, and (3) industrial processes such as the production and consumption of minerals and chemicals, accounting for about 15% of total U.S. CO2 emissions and 12% of total ...

دراینمقاله،میزانو ارزش انتشارگازهایگلخانه‌ای اکسید‌نیتروس(N2O) و دی‌اکسید‌کربن(CO2)حاصلازتولید حبوبات منتخب ایران (شامل نخود، لوبیا و عدس) با استفاده از مدل GHGE،برایسالزراعی91-90برآورد شده است.نتایج نشان‌داد که استان‌هایفارسوبوشهر، به‌ترتیبباتولیدسالانه271/79 و 004/0 تنN2O، بیشترینوکمترینمیزانتولیدگاز گلخانه‌ایN2Oرا دارامی‌باشند. همچنین استان‌هایلرستانوبوشهر نیز به‌ترتیب باتولیدسالانه83/10327 و33/1‌تنCO2،بیشترینوکمترینمیزانتولیدگاز گلخانه‌ایCO2را به‌خود اختصاص داده‌اند. مجموعهزینه‌هایزیست‌محیطی انتشار گازهای گلخانه‌ای N2O و CO2 کلکشورنیزحدود705/32‌میلیاردریالبرآوردگردید. باتوجهبه یافته‌ها، مدیریت کودهای نیتروژنه مصرفی در مزارعوتوسعهسیاست‌کاهشمیزانانتشاربه‌همراه مالیات زیست‌محیطی انتشار گازهای گلخانه‌ای بر سطوح مختلف تولید پیشنهاد شده ‌است. واژه‌های کلیدی: اکسید‌نیتروس، دی‌اکسید‌کربن، حبوبات، گازهای گلخانه‌ای

انتشار گازهای گلخانه‌ای و اثرات آن بر گرمایش جهانی یکی از چالش‌های جدی کشورهای توسعه‌یافته و درحال‌توسعه محسوب می‌شود. بر اساس پیمان کیوتو، کشورهای مختلف موظف به محاسبه و اعلام میزان انتشار گازهای گلخانه‌ای شدند. بررسی میزان انتشار گازهای گلخانه‌ای کشورهای مختلف این امکان را فراهم می‌آورد تا ضمن ارائه تصویری از سهم کشورها در تولید گازهای گلخانه‌ای، جایگاه ایران نیز در این مجموعه مشخص شود. این مقاله تلاش دارد تا میزان و ارزش انتشار گازهای گلخانه‌ای اکسید نیتروس (N2O) و دی‌اکسید کربن (CO2) حاصل از دانه های روغنی تولیدی منتخب در ایران (سویا، کلزا، ذرت دانه ای و سایر دانه های روغنی) را با استفاده از مدل GHGE، برای سال زراعی 91-90 برآورد نماید. نتایج نشان داد استان‌های خوزستان و زنجان به ترتیب، با تولید سالانه 49/341 و 004/0 تن، بیش ترین و کم ترین میزان تولید گاز گلخانه‌ای N2O را در سطح کشور دارا می‌باشند. همچنین استان‌های گلستان و هرمزگان نیز به ترتیب، با تولید سالانه 47/7841 و 24/0 تن دی‌اکسید کربن بیش ترین و کم ترین میزان تولید گاز گلخانه‌ای CO2 را به خود اختصاص داده‌اند. مجموع هزینه‌های انتشار گازهای گلخانه‌ای N2O و CO2 کل کشور نیز حدود 331/27 میلیارد ریال برآورد گردید. باتوجه به یافته ها، اصلاح و تغییر شیوه‌های مدیریتی کشاورزی نسبت به سطح زیرکشت محصولات زراعی، مدیریت و افزایش کارایی کودهای ازته مصرفی در مزارع و توسعه سیاست‌های کاهش میزان انتشار به‌همراه مالیات زیست-محیطی انتشار گازهای گلخانه ای به سیاست‌گذاران این عرصه پیشنهاد شد.

Nowadays, the global climate change has been a worldwide concern and the greenhouse gases (GHG) emissions are considered as the primary cause of that. The United Nations Conference on Environment and Development (UNCED) divided countries into two groups: Annex I Parties and Non-Annex I Parties. Since Iran and all other countries in the Middle East are among Non-Annex I Parties, they are not required to submit annual GHG inventory report. However, the global climate change is a worldwide phenomenon so Middle Eastern countries should be involved and it is necessary to prepare such a report at least unofficially. In this paper the terminology and the methods to calculate GHG emissions will first be explained and then GHG emissions estimates for the Iranian power plants will be presented. Finally the results will be compared with GHG emissions from the Canadian electricity generation sector. The results for the Iranian power plants show that in 2005 greenhouse gas intensity for steam power plants, gas turbines and combined cycle power plants were 617, 773, and 462 g CO2eq/kWh, respectively with the overall intensity of 610 g CO2eq/kWh for all thermal power plants. This GHG intensity is directly depend on efficiency of power plants. Whereas, in 2004 GHG intensity for electricity generation sector in Canada for different fuels were as follows: Coal 1010, refined petroleum products 640, and natural gas 523 g CO2eq/kWh, which are comparable with same data for Iran. For average GHG intensity in the whole electricity generation sector the difference is much higher: Canada 222 vs. Iran 610g CO2eq/kWh. The reason is that in Canada a considerable portion of electricity is generated by hydro-electric and nuclear power plants in which they do not emit significant amount of GHG emissions. The average GHG intensity in electricity generation sector in Iran between 1995 and 2005 experienced 13% reduction. While in Canada at the same period of time there was 21% increase. However, the results demonstrate that still there are great potentials for GHG emissions reduction in Iran’s electricity generation sector.

Purpose. Development and verification of a method for calculating and forecasting CO2 emissions from coal combustion at thermal power plants based on proximate analysis data. Calculation of gross and specific CO2 emissions per unit of output energy and mass of coal consumed at Ukrainian thermal power plants (TPPs). Methodology. Methods of mathematical statistics were used for processing the data of ultimate and proximate analysis of 170samples of A, L, G, and LFG coal ranks with low heat value on operating state in the range of 17.2 to 31.0 MJ/kg and ash content on dry state (Ad) in the range of 3.8 to 38.0% to determine relationships between carbon emission factors (kc), calorific value, and ash content. Findings. The values of emission factors and gross CO2 emissions for mixtures of coals of grades A and L, G and LFG at Ukrainian TPPs in 20172021 were calculated. For 2021, the average value of for coals of grades G and LFG was 94,128 g/GJ, and for coals of grades A and L it was 104,987 g/GJ. Gross CO2 emissions at Ukrainian TPPs have been in the range of 3849million tons in recent years, and their annual reduction is due to a decrease in energy production and fuel consumption at TPPs, primarily of grades A and L. Originality. Empirical dependencies kc for steam coal of different ranks are determined in the form of The coefficients a, b, and c are determined for grades A, L, G, and LFG and their mixtures. The relationship between the carbon content in coal and the low heat value for coal is linear: where K is a coefficient depending on the coal grade. The values of K are determined for coal of grades A, L, G, and LFG. Practical value. Verification of the created method shows that the calculation error is less than 1.0%. This is in line with the requirements of the Monitoring Procedure and Directive 2003/87/EC. In 2021, the specific CO2 emission per unit of output energy at TPPs in Ukraine was 1,084 g/kWh for all ranks of steam coal. The values of specific CO2 emissions per unit mass of consumed coal were 1.94 t/t for coals of all grades, 1.91 t/t for grades G and LFG, and 2.21 t/t for grades A and L. The official annual reports of the Ministry of Energy of Ukraine contain information on the amount of produced electricity, consumed coal, and forecast balances of electricity production at TPPs, therefore, the values of specific emissions established by us are convenient to use for estimating and forecasting carbon dioxide emissions.

Legislation to cap and trade greenhouse gas (GHG) emissions was approved by a 219-212 vote of the United States House of Representatives on June 26, 2009. Cap and trade policy articulated in the American Clean Energy and Security (ACES) act of 2009 regulates GHGs including carbon dioxide, methane, nitrous oxide, sulfur hexafluoride, hydrofluorocarbons, perfluorocarbons and nitrogen trifluoride. Debate over the ACES act focused heavily on economic issues contrasted against concerns about climate change1. However, discussion largely ignored the potential for cap and trade legislation to contribute to reductions in levels of other harmful air pollutants, such as sulfur dioxide, particulate matter, and ozone precursors that share emission sources with GHGs. Under the bill, domestic GHG emissions are to be capped at 2005 annual levels, and reduced to 17% of those marks by 20502. The bill provides for an initial round of pollution permits to be made available, some free, others at auction. Subsequently, these permits can be bought and sold in the open market by organizations such as utility companies and manufacturing firms. A key provision in the ACES act requires the president to impose tariffs on countries that do not implement similar regulations on GHG emissions. While other potentially viable legislation, such as a tax on carbon emissions, has been proposed3, the current cap and trade legislation is the first bill to pass in either the House or Senate. The greenhouse gases regulated under the ACES act do not generally pose serious direct health risks. For example, nitrous oxide is used in dental procedures, and carbon dioxide is an ingredient in carbonated beverages. Other GHGs, like nitrogen trifluoride and sulfur hexafluoride, are not harmful at their current concentration levels, but can be hazardous to persons working with them if safety precautions are not taken. Instead, substantial human health benefits from cap and trade legislation could potentially come from reductions in ambient levels of harmful pollutants, such as particulate matter and ozone, that share emissions sources with GHGs. For example, 94% of CO2 emissions in the US result from combustion of fossil fuels, with electricity generation and transportation alone comprising nearly 70%. These are also the leading source of sulfur dioxide, fine particles having diameter small than 2.5 micrometers (PM2.5), and precursors to ozone such as mono-nitrogen oxides (NOx)4. While the time scale for potential impacts of cap and trade legislation on climate change and related health benefits is likely decades or centuries, ancillary air pollution mitigation could have immediate health benefits. In two nationwide epidemiological studies, daily levels of ambient ozone and PM2.5 have been linked to increased risk of cardiovascular and respiratory mortality5 and to increased risk of emergency hospital admissions, especially for heart failure6, respectively. Estimates of the potential health benefits attributable to reductions in harmful air pollutants resulting from mitigation of GHG emissions, at the city, region and national, have been substantial7. While US cap and trade legislation would likely reduce domestic air pollution levels, two caveats deserve consideration. First, methods for reducing GHG emissions typically reduce air pollution levels, but not always. This problem can be highlighted using airplanes as an example8. Two methods to reduce CO2 emissions from airplanes are to decrease aircraft weight or increase engine combustion temperatures. The former reduces both GHG and air pollution emissions, whereas the later reduces GHG emissions at the cost of increasing precursors to ozone. In the broader context of energy production, it is likely cap and trade legislation would drive a shift away from fossil fuel combustion to sources such as solar technology that produce much less air pollution. However, the exact technology development path is still uncertain. A second problem is the potential for domestic cap and trade legislation to transfer US emissions to newly industrialized nations. Countries facing lower production costs associated with looser regulations on GHG emissions would have an economic advantage over manufacturing industries in the US. However, increased air pollution from new manufacturing could be a key public health issue for developing regions, such as China's Pearl River delta, where air pollution levels are already much higher than standards in the US9. The economic and physical systems that would be affected by cap and trade legislation are extremely complex, and impacts on air pollution will have to be considered in a broad context. For example, while the absence of tariffs would likely push manufacturing, air pollution and related negative health effects to developing regions, those regions might experience health benefits associated with increased per capita income. The discussion is similarly complex in the physical domain. For example, some air pollutants, such as sulfate particulate matter, can contribute to short term climate cooling. Though still somewhat unclear, there is an emerging debate over the possibility that air pollution mitigation could actually exacerbate global warming in the short term10. While it faces potentially significant opposition and alteration in the Senate, the cap and trade bill recently passed in the House has progressed further through Congress than any other similar legislation. There is tremendous potential for legislation regulating GHG emissions, via cap and trade or other strategies, to simultaneously decrease emissions of harmful air pollutants and reduce morbidity and mortality attributable to cardiovascular and respiratory illness. Such improvements in public health have been linked to economic benefits from recovered workforce productivity8, and add important support for progress on cap and trade legislation versus delayed action.

Major US electric utility climate pledges have the potential to collectively reduce power sector emissions by one-third

In recent years, greenhouse gas (GHG) emissions and their potential effects on the global climate change have been a worldwide concern. Based on International Energy Agency (IEA), power generation contributes half of the increase in global GHG emissions in 2030. In the Middle East, Power generation is expected to make the largest contribution to the growth in carbon-dioxide emissions. The share of the power sector in the region’s total CO2 emissions will increase from 34% in 2003 to 36% in 2030. Therefore, it is very important to reduce GHG emissions in this industry. The purpose of this paper is to examine greenhouse gas emissions reduction potentials in the Iranian electricity generation sector through fuel switching and adoption of advanced power generation systems and to compare these potentials with Canadian electricity generation sector. These two countries are selected because of raw data availability and their unique characteristics in electricity generation sector. To achieve this purpose two different scenarios have been introduced: Scenario #1: Switching existing power stations fuel to natural gas. Scenario #2: Replacing existing power plants by natural gas combined-cycle (NGCC) power stations (The efficiency of NGCC is considered to be 49%). The results shows that the GHG reduction potential for Iranian steam power plants, gas turbines and combined cycle power plants in first scenario are 9.9%, 5.6%, and 2.6%, respectively with the average of 7.6%. For the second scenario the overall reduction of 31.9%, is expected. The average reduction potential for Canadian power plants for scenario number 1 and 2 are 33% and 59%, respectively. As it can be seen, in Canada there are much higher potentials to reduce GHG emissions. The reason is that in Canada majority of power plants use coal as the primary fuel. In fact almost 73% of electricity in thermal power stations is generated by coal. Whereas in Iran almost all power plants (with some exceptions) are dual fuels and 77% of energy consumed in Iran’s thermal power plants come from natural gas. Also, 21% of total electricity generated in Iran is produced by combined-cycle power plants.

Low-carbon production of iron and steel: Technology options, economic assessment, and policy

Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California Energy Commission (Energy Commission) related to the Registry in three areas: (1) assessing the availability and usefulness of industry-specific metrics, (2) evaluating various methods for establishing baselines for calculating GHG emissions reductions related to specific actions taken by Registry participants, and (3) establishing methods for calculating electricity CO2 emission factors. The third area of research was completed in 2002 and is documented in Estimating Carbon Dioxide Emissions Factors for the California Electric Power Sector (Marnay et al., 2002). This report documents our findings related to the first areas of research. For the first area of research, the overall objective was to evaluate the metrics, such as emissions per economic unit or emissions per unit of production that can be used to report GHG emissions trends for potential Registry participants. This research began with an effort to identify methodologies, benchmarking programs, inventories, protocols, and registries that u se industry-specific metrics to track trends in energy use or GHG emissions in order to determine what types of metrics have already been developed. The next step in developing industry-specific metrics was to assess the availability of data needed to determine metric development priorities. Berkeley Lab also determined the relative importance of different potential Registry participant categories in order to asses s the availability of sectoral or industry-specific metrics and then identified industry-specific metrics in use around the world. While a plethora of metrics was identified, no one metric that adequately tracks trends in GHG emissions while maintaining confidentiality of data was identified. As a result of this review, Berkeley Lab recommends the development of a GHG intensity index as a new metric for reporting and tracking GHG emissions trends.Such an index could provide an industry-specific metric for reporting and tracking GHG emissions trends to accurately reflect year to year changes while protecting proprietary data. This GHG intensity index changes while protecting proprietary data. This GHG intensity index would provide Registry participants with a means for demonstrating improvements in their energy and GHG emissions per unit of production without divulging specific values. For the second research area, Berkeley Lab evaluated various methods used to calculate baselines for documentation of energy consumption or GHG emissions reductions, noting those that use industry-specific metrics. Accounting for actions to reduce GHGs can be done on a project-by-project basis or on an entity basis. Establishing project-related baselines for mitigation efforts has been widely discussed in the context of two of the so-called ''flexible mechanisms'' of the Kyoto Protocol to the United Nations Framework Convention on Climate Change (Kyoto Protocol) Joint Implementation (JI) and the Clean Development Mechanism (CDM).

Abstract. This paper summarizes currently available data on greenhouse gas (GHG) emissions from African natural ecosystems and agricultural lands. The available data are used to synthesize current understanding of the drivers of change in GHG emissions, outline the knowledge gaps, and suggest future directions and strategies for GHG emission research. GHG emission data were collected from 75 studies conducted in 22 countries (n = 244) in sub-Saharan Africa (SSA). Carbon dioxide (CO2) emissions were by far the largest contributor to GHG emissions and global warming potential (GWP) in SSA natural terrestrial systems. CO2 emissions ranged from 3.3 to 57.0 Mg CO2 ha−1 yr−1, methane (CH4) emissions ranged from −4.8 to 3.5 kg ha−1 yr−1 (−0.16 to 0.12 Mg CO2 equivalent (eq.) ha−1 yr−1), and nitrous oxide (N2O) emissions ranged from −0.1 to 13.7 kg ha−1 yr−1 (−0.03 to 4.1 Mg CO2 eq. ha−1 yr−1). Soil physical and chemical properties, rewetting, vegetation type, forest management, and land-use changes were all found to be important factors affecting soil GHG emissions from natural terrestrial systems. In aquatic systems, CO2 was the largest contributor to total GHG emissions, ranging from 5.7 to 232.0 Mg CO2 ha−1 yr−1, followed by −26.3 to 2741.9 kg CH4 ha−1 yr−1 (−0.89 to 93.2 Mg CO2 eq. ha−1 yr−1) and 0.2 to 3.5 kg N2O ha−1 yr−1 (0.06 to 1.0 Mg CO2 eq. ha−1 yr−1). Rates of all GHG emissions from aquatic systems were affected by type, location, hydrological characteristics, and water quality. In croplands, soil GHG emissions were also dominated by CO2, ranging from 1.7 to 141.2 Mg CO2 ha−1 yr−1, with −1.3 to 66.7 kg CH4 ha−1 yr−1 (−0.04 to 2.3 Mg CO2 eq. ha−1 yr−1) and 0.05 to 112.0 kg N2O ha−1 yr−1 (0.015 to 33.4 Mg CO2 eq. ha−1 yr−1). N2O emission factors (EFs) ranged from 0.01 to 4.1 %. Incorporation of crop residues or manure with inorganic fertilizers invariably resulted in significant changes in GHG emissions, but results were inconsistent as the magnitude and direction of changes were differed by gas. Soil GHG emissions from vegetable gardens ranged from 73.3 to 132.0 Mg CO2 ha−1 yr−1 and 53.4 to 177.6 kg N2O ha−1 yr−1 (15.9 to 52.9 Mg CO2 eq. ha−1 yr−1) and N2O EFs ranged from 3 to 4 %. Soil CO2 and N2O emissions from agroforestry were 38.6 Mg CO2 ha−1 yr−1 and 0.2 to 26.7 kg N2O ha−1 yr−1 (0.06 to 8.0 Mg CO2 eq. ha−1 yr−1), respectively. Improving fallow with nitrogen (N)-fixing trees led to increased CO2 and N2O emissions compared to conventional croplands. The type and quality of plant residue in the fallow is an important control on how CO2 and N2O emissions are affected. Throughout agricultural lands, N2O emissions slowly increased with N inputs below 150 kg N ha−1 yr−1 and increased exponentially with N application rates up to 300 kg N ha−1 yr−1. The lowest yield-scaled N2O emissions were reported with N application rates ranging between 100 and 150 kg N ha−1. Overall, total CO2 eq. emissions from SSA natural ecosystems and agricultural lands were 56.9 ± 12.7 × 109 Mg CO2 eq. yr−1 with natural ecosystems and agricultural lands contributing 76.3 and 23.7 %, respectively. Additional GHG emission measurements are urgently required to reduce uncertainty on annual GHG emissions from the different land uses and identify major control factors and mitigation options for low-emission development. A common strategy for addressing this data gap may include identifying priorities for data acquisition, utilizing appropriate technologies, and involving international networks and collaboration.

Comparing CO2 emissions impacts of electricity storage across applications and energy systems

Indonesia has targeted 29 % Greenhouse gas (GHG) emissions reduction in 2030 and Industry is one of the big two contributors for GHG emissions. As an industry, mining is an energy-intensive industry, and reducing energy consumption is one of the strategies to improve mining environmental performance. The aim of this paper is to estimate the GHG emission reduction in a mining project through energy reduction initiatives. A copper mine in Indonesia with processing plant capacity of 120,000 t/d and operate 111 Caterpillar 793C Haul Truck was taken as a case study. This mine site has two sources of an electricity namely coal-fired power plant with 112 MW output and diesel power plant with 45 MW output. The analysis method for calculating CO2 emission is using IPCC method where fuel consumption and emission factor are two main variables for GHG emissions. Business as usual scenario (TIER 1) showed that the average of diesel fuel consumption for fleets operation generated 294,006 t CO2-eq/y. A coal-fired power plant with average coal consumption of 350 t/d/unit generated 1.15 Mt CO2-eq/y and diesel power plant consumed 4.35 ML/y produced 11,632 t CO2-eq/y. Two energy initiative programs were identified namely fuel conversion and used oil utilisation program. The initiative scenario focused on substituting, reducing and reusing of fossil fuels including coal, diesel fuel, and used oil. This scenario was estimated to contribute the carbon emission reduction (t CO2-eq) of 258,381 annually. The involvement of mining industry in carbon emission reduction is not only helping Indonesia in achieving its GHG emissions reduction target but also increases mine site environmental performance and company image.

Rivers play an important role in greenhouse gas emissions. Over the past decade, because of global urbanization trends, rapid land use changes have led to changes in river ecosystems that have had a stimulating effect on the greenhouse gas production and emissions. Presently, there is an urgent need for assessments of the greenhouse gas concentrations and emissions in watersheds. Therefore, this study was designed to evaluate river-based greenhouse gas emissions and their spatial-temporal features as well as possible impact factors in a rapidly urbanizing area. The specific objectives were to investigate how river greenhouse gas concentrations and emission fluxes are responding to urbanization in the Liangtan River, which is not only the largest sub-basin but also the most polluted one in Chongqing City. The thin layer diffusion model method was used to monitor year-round concentrations of pCO2, CH4, and N2O in September and December 2014, and March and June 2015. The pCO2 range was (23.38±34.89)-(1395.33±55.45) Pa, and the concentration ranges of CH4 and N2O were (65.09±28.09)-(6021.36±94.36) nmol·L-1 and (29.47±5.16)-(510.28±18.34) nmol·L-1, respectively. The emission fluxes of CO2, CH4, and N2O, which were calculated based on the method of wind speed model estimations, were -6.1-786.9, 0.31-27.62, and 0.06-1.08 mmol·(m2·d)-1, respectively. Moreover, the CO2 and CH4 emissions displayed significant spatial differences, and these were roughly consistent with the pollution load gradient. The greenhouse gas concentrations and fluxes of trunk streams increased and then decreased from upstream to downstream, and the highest value was detected at the middle reaches where the urbanization rate is higher than in other areas and the river is seriously polluted. As for branches, the greenhouse gas concentrations and fluxes increased significantly from the upstream agricultural areas to the downstream urban areas. The CO2 fluxes followed a seasonal pattern, with the highest CO2 emission values observed in autumn, then successively winter, summer, and spring. The CH4 fluxes were the highest in spring and the lowest in summer, while N2O flux seasonal patterns were not significant. Because of the high carbon and nitrogen loads in the basin, the CO2 products and emissions were not restricted by biogenic elements, but levels were found to be related to important biological metabolic factors such as the water temperature, pH, DO, and chlorophyll a. The carbon, nitrogen, and phosphorus content of the water combined with sewage input influenced the CH4 products and emissions. Meanwhile, N2O production and emissions were mainly found to be driven by urban sewage discharge with high N2O concentrations. Rapid urbanization accelerated greenhouse gas emissions from the urban rivers, so that in the urban reaches, CO2/CH4 fluxes were twice those of the non-urban reaches, and all over the basin N2O fluxes were at a high level. These findings illustrate how river basin urbanization can change aquatic environments and aggravate allochthonous pollution inputs such as carbon, nitrogen, and phosphorus, which in turn can dramatically stimulate river-based greenhouse gas production and emissions; meanwhile, spatial and temporal differences in greenhouse gas emissions in rivers can lead to the formation of emission hotspots.

Do soil conservation practices exceed their relevance as a countermeasure to greenhouse gases emissions and increase crop productivity in agriculture?