Abstract
Intermediate volatility organic compounds (IVOCs) have a significant contribution to the formation of secondary organic aerosols (SOA) in the atmosphere, but are not included in the current emission inventory. In this study, IVOC emissions from vehicles are estimated for the Yangtze River Delta region (YRD) for 2017 based on two methods:the emission factor method and the IVOCs/POA scaling factor method. Uncertainties in the estimated IVOCs emissions and the impact on their potential formation are discussed. The results based on the emission factor method showed that the total vehicular IVOCs emission in the YRD in 2017 was 35800 tons, and that the formation potential of SOA was an estimated 695 tons. IVOCs emissions from trucks accounted for>70% of total IVOCs emissions in most cities in the YRD region. In terms of fuel type, IVOCs emissions from diesel vehicles were much higher than of those from gasoline vehicles. Results based on the IVOCs/POA scaling factor method showed that the emissions calculated by different combinations of IVOCs/POA ratios and POA/PM2.5 ratios that could vary significantly, with a maximum of 64.2×104 tons and a minimum of just 5.2×104 tons. The resultant SOA formation potential was 1.55×104 tons and 1032 tons for the maximum and minimum, respectively. This study shows that the results of IVOCs emissions based on different estimation methods are associated with large uncertainties, which could directly affect the simulation results of SOA in subsequent air quality models. Therefore, it is necessary to use different inventory results in air quality models and perform model evaluation of SOA in order to obtain more accurate IVOCs emission inventories of vehicles in the YRD region.
Published Version
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