Emission characteristics of size distribution, chemical composition and light absorption of particles from field-scale crop residue burning in Northeast China

Qinglu Wang,Lili Wang,Xingru Li,Jinyuan Xin,Zirui Liu,Yang Sun,Jingda Liu,Yanjun Zhang,Wei Du,Xin Jin,Tianran Zhang,Shuiqiao Liu,Quan Liu,Jie Chen,Miaomiao Cheng,Yuesi Wang

doi:10.1016/j.scitotenv.2019.136304

Abstract

Crop residue burning in China increased significantly in the last decade, especially it took up a majority in Northeast China, which plays an important role of severe haze pollution. Hence, two main types of crop residues (corn and rice straw) were chosen to characterize the particle number concentration, chemical components of fine particulate matter and optical properties of carbonaceous aerosols by a suite of fast-response online portable instruments, together with offline sampling and analysis, during the field-based combustion experiments in Northeast China. For the range of 250 and 2500 nm, more particles were emitted from rice straw burning than those from corn straw burning, and the time-averaged number concentration of particles during the flaming process was approximately 2 times higher than that during the smoldering process for these two straws. Organic carbon (OC), elemental carbon (EC) and water-soluble ions were the most abundant components and accounted for 42.5 ± 7.5%, 7.7 ± 1.7% and 18.0 ± 3.4% of the PM2.5, respectively. Furthermore, rice straw burning emitted higher OC and lower Cl− and K+ than those from corn straw burning. The average absorption Ångström exponent (AAE) of carbonaceous aerosols was 2.1 ± 0.3, while the AAE of brown carbon (BrC) was 4.7 ± 0.4 during the whole burning process. On average, BrC contributed to 63% and 20% of the total light absorption at 375 nm and 625 nm, respectively. Parameterization of BrC absorption revealed that the fraction of absorption from BrC has a reasonably good correlation with EC/OC (−0.84) and AAE (0.94) at 375 nm. Generally, combustion conditions can affect the optical properties of carbonaceous aerosols, and a negative correlation (−0.77) was observed between the AAE and modified combustion efficiency; in addition, the percentage of absorption due to BrC were lower at the flaming phase.

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