Elucidating the microscopic origin of electrochemical corrosion and electrical conductivity by lattice response to severe plastic deformation in Al-Mn-Si alloy

Abstract

Al-Mn-Si specimens were underwent SPD by CGP, cold-rolling and their combined paths. Acquired OM and SEM micrographs revealed that random distribution of intermetallic precipitates beside their fragmentation under heavy imposed strains deteriorated particles’ influence on the electrochemical corrosion and inhibited pitting. Analysis of XRD patterns pointed out that post-rolling of CGPed sheets resulted in dynamic annihilation of dislocations and accordingly crystal lattice swelling (d-spacing increase) due to dynamic recrystallization. From polarization results, crystallites’ refinement along with density increment of sub-grain boundaries within structure as a consequence of SPD beside dislocation density enhancement accelerated corrosion. Outputs of four-point probe electrical conductivity examination indicated that apart from the employed processing, lattice compaction and atomic layers approach would limit the electrons’ mobility space and hence reduce the conductivity of material. In this regard, combined effects of CGP and rolling as employed dual-straining route on Al-Mn-Si alloy enhanced the electrical conductivity by d-spacing growth.