Abstract

HighlightsMechanistic understanding of ion transport phenomena in composite solid-state electrolytes (CSEs) for practical solid-state batteries is conducted.Percolation threshold formation of the inorganic (LPSCl) phase in the CSEs depends on elasticity of the gel polymer electrolyte (GPE) phase.Manipulating the solvation/desolvation behavior of the GPE phase facilitates ion conduction across the LPSCl-GPE interfaces.

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