Elimination of interferences in determination of platinum and palladium in environmental samples by inductively coupled plasma mass spectrometry

Abstract

Various approaches were evaluated in order to eliminate the spectral interferences noted when Pt and Pd has to be determined in environmental dust samples by ICP-MS. The chemical separation of Pt and Pd from the matrix components on ion-exchange resins was applied. The performance of cation-exchange resins (Dowex 50 WX-8, Dowex 50 WX-2, Dowex HCR-S, Varion KS, Cellex-P) for the separation of interfering ions was then examined. It was found that Dowex 50 WX-8 shows best performance. The effects of mass, mesh number of resin and concentration of Cl − ions on matrix separation were also studied. Another approach was to use the anion-exchange sorbent Cellex-T, which allows almost total retention of both analytes followed by their elution with 0.1 mol L −1 thiourea in 1 mol L −1 HCl. This procedure however can be used only for platinum determination by ICP-MS. The accuracy of proposed procedures was confirmed by the analysis of certified material BCR-723, and then it was used for determination Pt and Pd in samples of road dust.