Eliminating pesticide quinalphos from surface waters using synthesized GO-ZnO nanoflowers: Characterization, degradation pathways and kinetic study

Abstract

The presence of highly toxic and persistent pesticides in water bodies causes serious problems to human beings as well as aquatic life. Quinalphos is one such widely used organophosphorus pesticide in agricultural fields. Herein, for degradation and mineralization of quinalphos, ZnO nanoflowers and their hybrid nanocomposite with graphene oxide have been synthesized. FESEM analysis confirmed the formation of ZnO nanoflowers over nanosheets of graphene oxide having a thickness of 20 ± 10 nm. GO-ZnO composite exhibited remarkable photocatalytic activity in comparison to pure ZnO. 98 % degradation of quinalphos was achieved using GO-ZnO nano-catalyst at 6 pH within 45 min of irradiations, whereas it was 80 % for bare ZnO nanoflowers. Higher degradation with hybrid nanocomposite was attributed to improved surface area (36 m2 g−1), a substantial reduction in bandgap energy from 3.10 to 2.90 eV and enhanced charge separation (e−/h+ pairs) after the addition of GO. Reaction kinetics study followed pseudo-first-order behaviour. Further, mineralization to the extent of 90 % in 90 min was confirmed by TOC analysis. Based on identified intermediates, using LCMS analysis, degradation pathways were proposed. The plausible pathways confirmed the presence of smaller and safer reaction intermediates supported by excitation of e− from nanocomposite followed by oxidation of quinalphos with huge free radicals. Overall, this study is significant in terms of using photocatalysis as a tertiary treatment of quinalphos pesticide wastewater at pH 6 in a short duration.