Abstract
Quaternary semiconductors in the kesterite phase are of keen interest for next-generation photovoltaics. For a given chemical composition, several idealized crystal structures are available, with quite different electronic band structures and gaps. Also complicating the picture are imperfections in the actual crystal structure realized during processing. The authors study Cu${}_{2}$ZnGeSe${}_{4}$ via ellipsometry and density functional theory, identifying its major optical features and relating them to structural imperfections. This work points the way to improved alloying and band-gap engineering.
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