Abstract
The electronic absorption spectra (UV-visible-NIR) of a range of molecular metal cluster compounds, including new spectra of Pt309(phen*)36O28 in solution and Au55(PPh3)12Cl6 in the solid state, are discussed and compared with the spectra of colloidal particles of the corresponding metals. We consider frontier orbital separations, the development of ‘interband’ absorptions, the possible appearance of molecular plasma resonances, and charge-transfer in the solid state.
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