Abstract
Theoretical investigations of forward and reverse photoelectron transfer in bichromophoric systems embedded in solid solution is presented. Respective equations for decay profiles of donor and radical pairs are presented. Assuming a specific Gaussian-like distribution function between donor and acceptor molecules, the decay profiles of donor and radical pairs were analyzed. The analysis of influence of excluded volume on photophysical observables is also presented. The results obtained show the importance of introduction of specific distribution functions in analysis of photoelectron transfer in bichromophoric systems.
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