Abstract
Single crystals of cupric 3-pyridine sulfonate diluted in the diamagnetic zinc compound were prepared and observed for paramagnetic resonance. The symmetry of the magnetic complex is orthorhombic, with two of the g values only slightly different. The ground state of the ion is dz2 which exhibits practically no orbital angular momentum along z. An analysis of the cupric hyperfine structure at room temperature has been performed, arriving at a value of the polarization of the core in very good agreement with the theoretical estimate. No nitrogen superhyperfine structure is resolved at room temperature, although experiments at 77°K show conclusively interaction with two equivalent nitrogens, which is interpreted in detail.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
