Electron Paramagnetic Resonance in HoxLu1−xB12 Dodecaborides

Abstract

The high-frequency (60 GHz) electron paramagnetic resonance is studied in HoxLu1−xB12 single crystals at low temperatures (2–80 K) in an applied magnetic field up to 7 T within a wide doping range, 0.01 ≤ x ≤ 1. These compounds are characterized by the presence of a low-temperature cage glass phase with random displacements of magnetic holmium ions from the centrosymmetric position in B12 boron cuboctahedra. For the samples with x ≥ 0.1, it is demonstrated that the electron paramagnetic resonance in the form of a single broad line with a g-factor of about 5 appears in the cage glass phase at T 0.3, the pronounced broadening of the resonance line and a steep decrease in the g-factor related to antiferromagnetic correlations is observed on cooling at T < 30 K. The performed simulation of the electron paramagnetic resonance spectra suggests the dominant role of the exchange interaction effects and positional disorder in determining the characteristic features of spin dynamics in HoxLu1−xB12.