Abstract
Rechargeable Li-S secondary batteries have received ever-increasing attention recently due to their high theoretical specific energy density, wide material sources, low cost and being environmental friendly. Thus, the Li-S battery is becoming the most promising candidate for energy storage devices. But the current research shows that the polysulfides formed as intermediates during the discharge process can dissolve easily into the electrolyte, which will result in shuttle phenomenon. On the one hand, the high solubility of polysulfides leads to the loss of active material; on the other hand, the shuttle mechanism results in reduced columbic efficiency and poor cycle ability. So suppressing the polysulfides dissolution along with inhibiting the occurrence of shuttle phenomenon can effectively improve the whole performance of lithium sulfur battery. In this paper, the electrolytes used effectively in Li-S batteries are reviewed in detail including the organic liquid electrolytes, ionic liquids electrolytes, solid-state electrolytes, gel-like electrolytes, microporous polymer electrolytes, composite-solid polymer electrolytes along with the glass-ceramic electrolytes. Furthermore, the possible development prospects are also discussed.
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