Abstract
The electrodeposition of BiSrCaCu alloyed films from non-aqueous bath was carried out onto fluorine doped tin oxide (FTO) coated MgO substrates. The BiSrCaCu complex was formed with sodium citrate, Ethylenediammine tetraacetic acid (EDTA), tartaric acid, and sodium nitrate. Black coloured deposits of BiSrCaCu with thickness of 4–6 μm were obtained for the deposition period of 30 minutes. The effect of complexing agents and other preparative parameters on electrodeposition potentials and consequently on microstructural properties are studied. The oxide films showed superconductivity with onset and zero resistivity temperatures of 95 K and 76 K respectively.
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