Abstract
P-type inorganic materials show great potential as the hole transport layers in perovskite solar cells due to their low cost and enhanced chemical stability. As a p-type semiconductor, although AgCuO2 has a high hole mobility, it has not received much attentions so far. Herein, we introduce a one-step synthesis of AgCuO2 nanocrystalline films on conductive substrates by electrochemical deposition and use them as hole transport layers in perovskite solar cells. The electrodeposited AgCuO2 films exhibit smooth and pin-hole free morphology with high transmittance and good conductivity. Ultraviolet photoelectron spectroscopy also shows that the energy level of the AgCuO2 film matches well with the perovskite layer. Finally, the inverted perovskite solar cells based on AgCuO2 obtain a power conversion efficiency of 10.24%. This is the first study to demonstrate the successful use of AgCuO2 in perovskite solar cells. Moreover, it can be predicted that the ternary AgCuO2 will open up a new path for inorganic hole transport materials in the field of solar cells.
Published Version
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