Abstract
A series of ruthenium and iron mononuclear complexes were prepared and their spectroeletrochemical behavior characterized on Optically Transparent Thin Layer Electrodes (OTTLE) and on Fluorine Doped SnO 2 (FTO) conductive glasses coated with Sb-doped nanocrystalline SnO 2. These systems display a reversible electrochemical response and offer potential application in electrochromic devices. On SnO 2 films distinct spectral changes are observed in a narrow potential range (−0.5/0.9 V vs SCE) with switching times of the order of 0.8 s.
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