Electrochemical surface reconstruction of Prussian blue-modified nickel sulfide to form iron-nickel bilayer hydroxyl oxides for efficient and stable oxygen evolution reaction processes

Abstract

The oxygen evolution reaction (OER) is an important semi-reaction in the electrocatalytic water splitting for hydrogen energy production, and the development of efficient and low-cost electrocatalysts to solve the problem of slow 4-electron transport kinetics in the OER process is key. In this work, a pre-electrocatalyst with the heterogeneous interfacial structure, Prussian blue-modified nickel sulfide with sulfur vacancies (PB/NS-Sv), was designed and then converted to iron-nickel bilayer hydroxyl oxides in oxygen-rich vacancies (FeOOH/NiOOH-Ov@NS) through electrochemical oxidative reconstruction to obtain a truly stable and efficient active material. The study utilized in situ Raman to observe the transition from PB/NS-Sv to FeOOH/NiOOH-Ov@NS during the reaction. The electronic density of states in FeOOH/NiOOH-Ov@NS is regulated by the bilayer hydroxyl metal oxide synergistic effect and the abundant oxygen defect of Mental-OOH-Ov, which significantly improves OER catalytic performance. FeOOH/NiOOH-Ov@NS requires a low overpotential of only 257 mV in 1 mol/L KOH at 100 mA cm−2 current density, has a small Tafel slope of 35.2 mV dec−1 and has excellent stability for 150 h at 100 mA cm−2 current density, making it a promising candidate for industrial applications.