Abstract
A controlled-potential electrolysis was performed on mononuclear palladium(II) complexes containing aromatic isocyanide (RNC) and diphosphine (diphos) ligands, [Pd(diphos)(RNC) 2 )] (PF6) 2 (3) (R=2,6-dimethylphenyl or 2,4,6-trimethylphenyl, diphos=cis-1,2-bis(diphenylphosphino)ethene (dppen), 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), or 1,4-bis(diphenylphosphino)butane (dppb)), which were derived from the reaction of PdCl 2 (COD) with diphos, RNC, and N 4 PF 6
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