Electrochemical NOx reduction and oxidation of HC and PM emissions from biodiesel fuelled diesel engines using electrochemically activated cell

Abstract

ABSTRACTNOx emission is produced during combustion of fuels at high temperature. Excessive release of NOx causes several effects on living organisms and environment. In this work, the efforts to reduce NOx emission by developing electrochemically activated cells (EACs) for a diesel engine fuelled with diesel and biodiesel fuel are discussed. EAC technique is vital after treatment technology attempted in this work to simultaneous control of NOx, HC, and PM emissions. In this method, two types of EACs were developed. The CuO–YSZ electrolyte and CuO–YSZ electrolyte with BaO coating were developed and tested with diesel and biodiesel exhaust. Compared with diesel fuel, use of biodiesel fuel increased NOx emission by 11% and PM emission was slightly reduced with biodiesel, which was due to the presence of fuel bond oxygen content in biodiesel. The investigation has demonstrated low-temperature activation of the EACs at 250–350°C which was due to the addition of CuO to YSZ. In this work, maximum NOx reduction was achieved for CuO–YSZ cells with BaO NOx storage and the simultaneous control of HC and PM emission also was observed in this technique. NOx reduction by EAC is a vital technique and can be retrofitted with any diesel engine for emission reduction.