Abstract
In this work we propose electrochemical lossy mode resonance (eLMR) as a powerful method for the detection of manganese (Mn) ions. The sensor is based on a simple planar waveguide (sodalime glass coverslip) coated with a thin layer of indium tin oxide (ITO) to obtain an optical resonance effect. Simultaneously, the ITO layer served as the working electrode in the cathodic stripping voltammetry (CSV) of Mn. The eLMR sensor is capable of simultaneously performing electrochemical (EC) and optical measurements, specifically lossy mode resonance (LMR), to monitor the growth of the adsorbed Mn layer on the ITO electrode and the electrochemically modulated diffusion layer. For Mn2+ ions, a limit of detection (LoD) of 1.26 ppb has been demonstrated using the EC method, whereas the optical method exhibited a LoD of 67.76 ppb. The results obtained indicate significant potential for application in molecular electrochemistry and studies focused on electrified interfaces.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
