Abstract
Perovskite materials have gained a lot of interest in solid oxide fuel cell (SOFC) applications owing to their exceptional properties; however, ideal perovskites exhibit proton conduction due to availability of low oxygen vacancies, which limit their application as SOFC electrolytes. In the current project, Sm was doped at the B-site of a BaCe0.7-xSmxZr0.2Y0.1O3-δ perovskite electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs). BaCe0.7-xSmxZr0.2Y0.1O3-δ electrolytes were synthesized through a cost-effective coprecipitation method and were sintered at a low sintering temperature. The effects of samarium (Sm) doping on the electrochemical performance of BaCe0.7-xSmxZr0.2Y0.1O3-δ were investigated. X-ray diffraction (XRD) analysis confirmed that the BaCe0.7-xSmxZr0.2Y0.1O3-δ electrolyte material retained the perovskite structure. The secondary phase of Sm2O3 was observed for BaCe0.4Sm0.3Zr0.2Y0.1O3-δ. Scanning electron microscopic (SEM) imaging displayed the dense microstructure for all the compositions, while prominent crystal growth was observed for composition x = 0.3. The formation of the perovskite structure and the presence of the hydroxyl groups of metal oxides for all the compositions were confirmed by Fourier transform infrared spectroscopy (FTIR). An increased symmetrical disturbance was also observed for the increased doping ratio of the Sm. Thermogravimetric analysis (TGA) of all the compositions showed no major weight loss in the SOFC operating temperature range. It was also noted that the conductivity of BaCe0.7-xSmxZr0.2Y0.1O3-δ gradually decreased with the increased contents of the Sm metal. The maximum power density of 390 mW cm−2, and an open-circuit voltage (OCV) of 1.0 V at 600 °C, were obtained, showing that BaCe0.7-xSmxZr0.2Y0.1O3-δ, synthesized by a cost-effective method and sintered at a low temperature, can be used as a proton-conducting electrolyte for IT-SOFCs.
Highlights
Introduction conditions of the Creative CommonsDuring the last decade, the energy demand increased exponentially because of worldwide economic developments and rapid industrial growth
This work is an effort to investigate BaCe0.7-x Smx Zr0.2 Y0.1 O3-δ as a stoichiometric material with the doping of Sm through the coprecipitation method. The objective of this project was to increase the conductivity of BaCe0.7-x Smx Zr0.2 Y0.1 O3-δ by increasing the oxygen vacancies with Sm doping, while retaining the perovskite structure using a costand time-effective synthesis route
The X-ray diffraction (XRD) spectra reveal that the synthesized BaCe0.7-x Smx Zr0.2 Y0.1 O3-δ protonconducting electrolyte retained a cubic perovskite structure
Summary
The energy demand increased exponentially because of worldwide economic developments and rapid industrial growth. The increased utilization of conventional energy sources is causing global warming because of the emission of harmful gases, such as CO2 , into the atmosphere [1,2,3]. The most critical and urgent concern for engineers and scientists is to find renewable energy sources that can overcome these problems. Renewable energy sources are preferred because of their low cost and environment-friendly aspects. Fuel cells are preferred among different energy sources because of their high efficiency, durability, fuel flexibility, and eco-friendly nature
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