Electrochemical behavior and effective extraction of Er in fused LiCl-KCl eutectic

Abstract

For the efficient electrolytic extraction of Er from spent nuclear fuel, a series of electrochemical methods was used to research the electrochemical behavior of Er(III) in the LiCl-KCl system on inert (Mo) electrode and on reactive (Ni) electrodes. On the inert Mo electrode, the reduction of Er(III) to Er(0) is a one-step with three-electron and quasi-reversible reaction process. Meanwhile, the apparent generation Gibbs free energy and activity coefficients of Er(III) on the inert electrode were determined. Thereafter, the electrochemical reduction of Er(III) on the Ni electrode was emphatically investigated. Er(III) is reduced at a corrected potential owing to the formation of Ni-Er alloys. In addition, thermodynamic parameters such as partial excess Gibbs free energy change of Er in Ni, activity and apparent generation Gibbs free energy of the Ni-Er alloys were determined by the electromotive force method. Finally, different Ni-Er alloys were produced using potentiostatic electrolysis on the Ni cathode by controlling different potentials. Moreover, electrolytic extraction was carried out on the Ni cathode at the potential of –2.0 V, and the separation efficiency of Er reaches 99.72%, which proves the practicability of separating Er from LiCl-KCl eutectic on the reactive Ni cathode.