Abstract
Let us consider two immiscible bodies in contact to form an interface. The highly polar body is positively charged, and the other is negatively charged (Koehn’s rule). However, the interface may have the adsorption of ions, dissociation of functional groups, orientation of dipoles, breaking down of chemical bonds, and so on. These affect the real charge densities at the interface, and hence the potential difference at the interface is not explained in terms of such simple dielectric properties of the bodies.
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