Abstract
The non-thermal response of neat dimethylimidazolium chloride salts and their binary mixtures with water have been investigated by means of non-equilibrium molecular dynamics simulation at an electric field intensity of 10 − 3 V/Å, in terms of electrical conductivity and dipolar relaxation (as metrics of translational and rotational response, respectively). Using Green-Kubo and transient time correlation function (TTCF) analysis, the electrical conductivity of each system has been estimated. It was found that the systems' conductivity at 450 K increased, while dipolar relaxation times for both water molecules and dimethylimidazolium ions decreased, with decreasing ionic liquid mole fraction. This indicates greater scope for accelerated response to external electric fields in less associated ionic liquids.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
