Abstract

Phthalocyanine compounds which have tetravalent atom at the center of phthalocyanine ring are synthesized. The effects of hexa-coordination on π-electron system and intermolecular interaction in crystals are observed in the absorption spectra of solutions and evaporated films. The electrical conductivity of silicon phthalocyanine is higher than those of germanium phthalocyanine and many other phthalocyanines. This characteristic is explained by the chemical affinity of silicon phthalocyanine to oxygen. Des composes de phthalocyanine qui ont tetravalent atom au centre du noyau de phthalocyanine etaient synthetises. Les effets de la hexa-coordination sur le systems des electrons π et la interaction intermoleculaire dans le cristal etaient observes dans les spectres d'absorption des solutions et des mince membrane. La conductibilite electrique de phthalocyanine de silicium etait plus haute que celle de phthalocyanine de germanium et un grand nombre de phthalocyanines. Cette caracteristique etait explique par une affinite chimique de phthalocyanine de silicium pour gaz oxygene.

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