Abstract

An efficient n-doped electron transport layer composed of 4,7-diphenyl-1,10-phenanthroline (BPhen) and dipotassium phthalate (PAK2) has been developed. By temperature-dependent admittance spectroscopy, the incorporation of PAK2 into BPhen is found to raise the Fermi level from 1.7eV to only around 0.5eV below BPhen’s lowest unoccupied molecular orbital, which further enhances the efficiency of electron injection from an Al cathode. When this n-doped layer is adopted in an organic light-emitting diode device, the green fluorescent 10-(2-benzothiazolyl)-1,1,7,7-tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-benzo[l]-pyrano[6,7,8-ij]quinolizin-11-one do-ped device can achieve a current efficiency of 16cd∕A and a power efficiency of 10.9lm∕W at 1000cd∕m2.

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