Electrical and dielectric properties of carbon black filled co-continuous two-phase polymer blends

Abstract

The electrical and dielectric properties of co-continuous polystyrene (PS)/poly(methylmethacrylate)(PMMA) blends loaded with carbon black (CB) of a special grade (BP 1000) have been studied. They strongly depend on the selective localization of the CB particles at the blend interface quite consistently with the double percolation concept. The interfacial localization of CB contributes to the stabilization of the phase morphology against thermal post treatment. Nevertheless, the sample annealing has a very favourable effect on the percolation threshold that decreases. The composition range in which phases are co-continuous is also increased by the addition of the filler. Dispersion of the conductance and the dielectric constant has been measured in the wide frequency range 10-4-108 Hz for blends containing 0-5 wt% CB. On the basis of these results, the mechanism of electrical transport (trapping, hopping, tunnelling, percolation) has been discussed in relation to the CB loading and the optimum loading has been identified for the electrical and dielectric properties to be stable and reproducible.