Elastic properties of C40 transition metal disilicides

Abstract

Room-temperature and low temperature elastic properties of hexagonal C40 transition metal disilicides, NbSi2 and TaSi2, have been studied using Resonant Ultrasound Spectroscopy (RUS). All five independent elastic stiffness constantscij for NbSi2 and single crystals have been obtained. The temperature dependence of thecij is normal but not large. The orientation dependence of the Young's and shear moduli was examined in comparison with other transition metal disilicides. The room temperature shear moduli in the {0001} plane, with values of 145.3 and 143.7 GPa for NbSi2 and TaSi2 respectively, are low relative to those in the equivalent pseudo hexagonal {110} close-packed plane for tetragonal C11b MoSi2 and WSi2. The isotropic elastic constants for polycrystalline materials were also calculated. The results show that the various moduli are all much higher than those of the constituent elements. The room temperature Poisson's ratios of NbSi2 and TaSi2 are 0.18 and 0.19, respectively, which are smaller than those of the constituent elements and smaller than most materials. The Debye temperatures,θD, were estimated to be 688 K for NbSi2 and 552 K for TaSi2. The elastic properties of C40 VSi2, NbSi2, TaSi2, and CrSi2 and C11b and WSi2 are compared and the possible influence on mechanical behavior discussed.