Abstract

AbstractWith the rapid development of industry, water pollution caused by lead has caused great harm to human health. In this study, alginate is used as a base and blended with biochar to form calcium alginate hydrogel beads with high mechanical properties through ionic cross‐linking. Besides, the material (BC/MCAC) is prepared by the material (C‐γ‐Fe2O3) as a magnetizing agent and to remove lead. Then, a series of batch experiments and material characterizations are performed to evaluate the adsorption process of the material. The results show that the maximum adsorption capacity of BC/MCAC to Pb(II) is 211.6 mg g−1 at pH = 7. The adsorption process is well described by the Langmuir adsorption isotherm and pseudo‐second‐order kinetic model. This indicates that the lead adsorbed by BC/MCAC is a monolayer chemisorption that occurs on a uniform surface. After three regeneration cycles, BC/MCAC is found to retain 82.37% of the lead adsorption capacity and has good regeneration ability. Lead is removed by BC/MCAC mainly through the complexation of oxygen‐containing functional groups, electrostatic interaction, and ion exchange. BC/MCAC allows for more sustainable use of the wastes and is expected to be a new type of lead adsorbent for industrial wastewater.

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