Efficient homogeneous photochemical water gas shift reaction catalysed under extremely mild conditions by novel iridium(III) complexes: [(η5-Me5C5)Ir(bpy)Cl]+, [(η5-Me5C5)Ir(bpy)H]+, and [(η5-Me5C5)Ir(phen)Cl]+(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline)

Raymond Ziessel

doi:10.1039/c39880000016

Efficient homogeneous photochemical water gas shift reaction catalysed under extremely mild conditions by novel iridium(III) complexes: [(η5-Me5C5)Ir(bpy)Cl]+, [(η5-Me5C5)Ir(bpy)H]+, and [(η5-Me5C5)Ir(phen)Cl]+(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline)

Raymond Ziessel

https://doi.org/10.1039/c39880000016

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Journal: J. Chem. Soc., Chem. Commun.	Publication Date: Jan 1, 1988
Citations: 59

#Turnover Numbers #Title Compounds #Light-driven Reaction #Room Temperature #Catalysts For Reaction #Iridium Hydride Species #Water Gas Shift #Iridium Hydride #Light-driven Water #Hydride Species

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The title compounds are shown to be active catalysts for the light-driven water gas shift reaction with turnover numbers up to 10 h–1; the iridium hydride species exhibits strong luminescence in solution at room temperature.

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Efficient homogeneous photochemical water gas shift reaction catalysed under extremely mild conditions by novel iridium(III) complexes: [(η5-Me5C5)Ir(bpy)Cl]+, [(η5-Me5C5)Ir(bpy)H]+, and [(η5-Me5C5)Ir(phen)Cl]+(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline)