Abstract

Zero-dimensional (0D) chiral hybrid metal halides (HMHs) with narrow-band circularly polarized luminescence (CPL) show considerable promise in three-dimensional displays. In this work, 0D (S/R-3MOR)3TbCl6 and (S/R-3MOR)3EuCl6 (abbreviated as S/R-TbCl, S/R-EuCl) enantiomers with characteristic rare-earth ion emissions are synthesized. S/R-TbCl and S/R-EuCl exhibit narrow-band green and red emissions with high photoluminescence quantum yields of (85-91)% and (48-52)%, respectively. These materials present distinct CPL signals with dissymmetry factors up to ±0.006 and ±0.009 for S/R-TbCl and S/R-EuCl, respectively. These chiroptical properties confer the potential for their applications in circularly polarized light-emitting diodes for future displays.

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