Efficient adsorptive removal of Co2+ from aqueous solution using graphene oxide.

Abstract

This study aimed to utilize synthesized graphene oxide (GO) for adsorptive removal of cobalt ions and investigate the adsorption mechanism using advanced techniques such as X-ray absorption spectra (XAFS). The GO was synthesized via an improved Hummers method, resulting in high surface area (93.7 m2/g) and abundant oxygen-containing functional groups. Various characterizations, including SEM, TEM, Raman, FT-IR, TG, potentiometric titrations, and N2 sorption-desorption measurements, were employed to characterize the GO. The adsorption behavior of GO towards Co2+ was investigated, and the results showed that the adsorption process followed a pseudo-second-order kinetic model and the Langmuir model, with a maximum sorption capacity of 93.7 mg/g. The adsorption process was chemisorption and endothermic, with GO showing adsorption selectivity order of Co2+ > Sr2+ > Cs+. Based on various characterizations such as X-ray absorption near-edge spectroscopy (XANES), extended X-ray absorption fine structure (EXAFS), FT-IR, and XPS, the sorption mechanism of Co2+ onto GO was discussed, with the results indicating that coordination and electrostatic interaction were the primary adsorption mechanisms, with oxygen-containing functional groups playing a vital role. The first coordinating atom for Co2+ was O, and the coordination environment was similar to that of cobalt acetate and CoO. Overall, this study provides comprehensive understanding of the adsorption behavior and mechanism of Co2+ onto GO, highlighting its potential as an effective adsorbent for removing nuclides from aqueous solution.