Abstract
This work addresses the role of chromia diffusion barrier on the combinatorial plating characteristics of Pd plating baths during fabrication of dense Pd/Cr2O3/porous stainless steel (PSS) composite membranes and is compared with those obtained during fabrication of Pd/PSS membranes. Cr2O3 was deposited by electroplating technique followed with oxidation at 700°C and Pd films were deposited using a novel Pd electroless plating process that provides optimal performance. Apart from providing similar process characteristics, the Pd/Cr2O3/PSS membrane provided 15.2% lower Pd film thickness in comparison with Pd/PSS membrane for similar pore densification values.
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