Abstract
Activation difficulty is the key problem limiting the application of TiFe-based hydrogen storage alloys. The addition of transition group elements helps to improve the activation properties of TiFe-based hydrogen storage alloy. In our previous work, the Ti 1.08 Y 0.02 Fe 0.8 Mn 0.2 alloy exhibits extremely high hydrogen storage capacity (1.84 wt%) at room temperature with excellent kinetic properties, but it still needs an incubation period of about 1500s. In this study, the composition of Ti 1.08 Y 0.02 Fe 0.8 Mn 0.2 Zr x ( x = 0, 0.02, 0.04, 0.06, 0.08) alloys was prepared by electromagnetic induction melting. The quantitative analysis of elements by energy dispersive spectrometer shows that in the second phase region containing Zr, the content of Ti element is significantly higher than that of Fe. Meanwhile, the first-principle calculation on Zr-doped TiFe system indicates that Zr is more attractive to substitute Ti than Fe. Therefore, the doping of Zr partially replaces the Ti. The solubility of Zr in TiFe is limited, when x ≤ 0.04, the alloy consists of pure TiFe phase. When x > 0.4, the excess Zr forms precipitates, which reduces the reversible hydrogen absorption and desorption capacity of the TiFe alloy. The addition of Zr significantly shortens the activation time and reduces the plateau pressure of TiFe alloys. The Ti 1.08 Y 0.02 Fe 0.8 Mn 0.2 Zr 0.04 alloy can be directly activated without the incubation period and its absolute values of enthalpy change (Δ H ) and entropy change (Δ S ) are minima (Δ H for 23.2 kJ/mol and Δ S for 83.1 J/mol/K). • TiFe-based alloys doping Zr was prepared by vacuum induction melting. • The solubility of Zr in TiFe is limited and excess Zr forms precipitates. • Adding Zr notably reduces the activation time and plateau pressure of TiFe alloys. • The Zr0.04 alloy can be activated without incubation period and absorb 1.6 wt% H.
Published Version
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