Abstract

been investigated. As-spun ribbons were examined by using X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). The results show that Ti and C additions enhance the glass forming ability and increase the crystallization temperature. XRD results of annealed ribbons indicate that Ti and C react to form TiC. The grain size was substantially refined by the addition of Ti due to the formation of Ti-enriched amorphous grain boundaries. The XRD and Atomic force microscope (AFM) technique results confirm that grains are in the size of less than 70 nm. Further addition of C enhanced the enrichment of Ti in the grain boundary phase, which led to the increase of the coercivity and the maximum energy product.

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