Abstract
Two novel artificial receptors based on diamide and bearing phenol group and copper(II) have been synthesized. Their anion-binding properties are evaluated for F −, Cl −, Br −, I −, AcO −, H 2PO 4 − and OH − by UV–vis and 1H NMR titration experiments to further elucidate the impact of phenol group and copper(II) on the chemistry of anion-recognition. Results indicate that the interacted model of fluoride anion with receptor 1 is different from other anions and the 1H NMR signals of receptor 2 occur changes after the addition of fluoride anion. This may be related with the small radius and strong electronegative property of fluoride. The receptors should have many chemical and analytical applications and the sensing principle should be widely applicable to the sensing of other receptors.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
