Abstract
AbstractWe have developed an environmentally friendly electrocatalytic protocol for the chlorination and bromination of electron‐rich arenes and aromatic boronic acids. The hydrogen bonding network generated from hexafluoroisopropanol (HFIP) and AcOH plays a vital role in the activation of halogen electrophiles generated electrochemically. The hydrogen bonding network also plays an essential role in the reduction of electrode passivation.
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