Effects of solution treatment on microstructural and mechanical properties of Al–Zn–Mg alloy by microalloying with Sc and Zr

Abstract

The effects of solution treatment on microstructural and mechanical properties of a novel Al–Zn–Mg alloy by microalloying with Sc and Zr were investigated by means of optical microscopy (OM), scanning electron microscopy (SEM), transition electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), differential scanning calorimeter (DSC), X-ray diffraction and tensile test, hardness measurement, respectively. The results show that solution treatment had a significantly effect on microstructural and mechanical properties. There exist lots of residual phases along rolling direction before solution treatment. With increasing solution temperature/time, the residual phases are dissolved into α-Al matrix gradually, and the number density of residual phases decreased. After solution treatment at 460°C/60 min and aging treatment at 120°C/24 h, the precipitated phase inside the grains are homogenously distributed η′ phase; the distribution of η precipitates is discontinuous and coarsened on the grain boundary. With the increase of solution temperature(≤470 °C) or solution time(≤60 min), the precipitated phases inside the grains began to become more diffuse, and the grain boundary precipitated phases also gradually become smaller. When solution temperature further increased to 490 °C or solution time increased to 120 min, the precipitated phases within the grains and on the grain boundary began to coarsen. In addition, there also exists lots of fine Al3(Sc, Zr) particles during aging treatment. Both tensile strength and hardness increase first and then decrease with increasing solution temperature or solution time. The optimum solution treatment is 470°C/60 min. The ultimate tensile strength, yield strength and elongation of the aged studied alloys reached a maximum value, 581 MPa, 561 MPa, and 10.1%, respectively.