Effects of soil properties on the remediation of diesel-contaminated soil by Triton X-100-aided washing.

Abstract

Although nonionic surfactant is widely used for petroleum-contaminated soil washing, there is no definite conclusion on the main soil factors which determine the removal of petroleum hydrocarbons from the soil. In this study, the influences of soil properties on Triton X-100-aided soil washing were investigated using 12 soils in China. The sorption characteristic of Triton X-100 on soils was described as well. The sorption isotherms of Triton X-100 on 12 typical soils were fitted to the Langmuir adsorption model, and the maximum sorption amount of Triton X-100 (Qmax) varied from 1.54 to 15.15mg/g. The removal rates of diesel for 12 soils were well fitted to the modified Michaelis-Menten equation, and the maximum removal rate of diesel (φmax) ranged from 62.92 to 90.36%. The correlation analysis indicated that the φmax is significantly correlated with the Qmax. The soil factors affecting diesel removal from soils followed the order of sand content > cation exchange capacity (CEC) > organic matter (OM) content > silt and clay content > SSA >> pH. The prediction model based on CEC, silt content, and pH explained 83.1% of variance of diesel removal from soils. This study will have important implication for successfully remediating organic-contaminated soil using nonionic surfactant-based soil washing.