Abstract
This study examined the effects of using ammonium chloride (NH4Cl), a chlorine quenching agent recommended by US Environmental Protection Agency method 552.3, on haloacetic acid (HAA) determination under different chloramination scenarios simulated in laboratory experiments. During the early reaction times for the surface water tested in this study (dissolved organic carbon of 3 mg/L), results showed that HAA concentration was overestimated up to 9 μg/L because of the use of NH4Cl. In all chloramination scenarios, positive errors decreased with increasing reaction time. Among the various quenching agents or methods tested, sodium arsenite (NaAsO2) and stoichiometric amounts of sodium sulfite (Na2SO3) were found to be appropriate for HAA determination in chloraminated samples. However, they have some limitations for use in practical applications. Immediate extraction of samples without using any quenching agent resulted in positive errors in HAA determination because of the low pH conditions (pH < 1) coupled with high temperature after the addition of sulfuric acid during HAA extraction. Adjusting sample pH to high values and using ascorbic acid for quenching chloramine were found to be unsuitable for HAA samples.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
